Chlorosulfonic Acid by R J Cremlyn

By R J Cremlyn

In view that its discovery in 1854, chlorosulfonic acid has verified that it's a really flexible reagent. it really is time-honored as a sulfonating and chlorosulfonating agent, quite of natural compounds, and it presents valuable artificial intermediates for lots of branches of undefined. This e-book presents a close, brand new account of the reactions of chlorosulfonic acid with aliphatic, fragrant and heterocyclic compounds; reactions with components and inorganic compounds also are mentioned, besides using the reagent as a strong acid catalyst and dehydrating agent. ultimately, the industrial makes use of and manufacture of chlorosulfonic acid are reviewed. The particular assurance during this booklet, coupled with the various references to contemporary paintings, will make sure that it's welcomed as a reference via man made chemists in, for instance, the pharmaceutical, agrochemical, plastic and detergent industries. Researchers and their scholars in academia also will locate it a necessary addition to their bookshelves.

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Chlorosulfonic Acid

Given that its discovery in 1854, chlorosulfonic acid has verified that it's a really flexible reagent. it really is familiar as a sulfonating and chlorosulfonating agent, rather of natural compounds, and it presents helpful artificial intermediates for lots of branches of undefined. This e-book presents an in depth, brand new account of the reactions of chlorosulfonic acid with aliphatic, fragrant and heterocyclic compounds; reactions with parts and inorganic compounds also are mentioned, in addition to using the reagent as a robust acid catalyst and dehydrating agent.

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A. S. Tubyarskaya, J ; Gen. Chem. USSR, 1962,32,3373; Chem. , 58, 11289. G. I. Rudakova, Im. Vyssh. Ucheb. , Khim. Khim. Tekhnol, 1972, 15(5), 716; Chem. , 77, 87401. 39 A. Carsadevall, A. Commeyras, P. Paillous and H. Collet, Bull. Chim. , 1970, 719; M. E. Pichl, Z. Anorg. Allg. , 1961, 335, 244. B. D. Zook, Synthetic Organic Chemistry, Wiley, New York, 1965, 822. M. W. Weston, Org. React. 0, 1946,3, 141. M. Suter, The Organic Chemistry of Sulfur, Wiley, New York, 1944. Reprinted edition by Intra-Science Research Foundation, Santa Monica, California, 1969, Chapter 3.

Chem. ,1949,71,453. CHAPTER 3 Reactions of Organic Sulfortyl Chlorides 1 Reactions with Nucleophilic Reagents As mentioned in Chapter 2, chlorosulfonic acid is a valuable reagent for the conversion of organic compounds into their sulfonyl chlorides. ’ The synthetic utility of sulfonyl chlorides depends on their ability to undergo substitution reactions with various nucleophilic reagents. Organic sulfonyl chlorides are generally liquids or low melting solids and they are not easily purified by recrystallization or distillation.

Patai and Z. Rappoport (eds), Wiley, Chichester, 1991, Chapter 16, 671. 37 K. Yang, I S . H. Kang and I. Lee, Bull. Korean Chem. , 1994, 15, 419; Chem. , 121, 107707. 38 K. S. Koo and I. Lee, J Phys. , 1995, 99, 15035; Chem. , 123, 2247420. G. Skrypnik, VF? N. Lyashchuk, Zh. Org. , 1993, 29, 1530; Chem. , 121, 107716. I Chem. ,Perkin Trans. S. W. Bentley, G. Llewellyn and K. Yang, . 1991, 1175. S. W. Bentley, G. J. Norman, Croat. Chem. Acta, 1992, 65, 575. S. W. H. Kang and I. Lee, J Chem. ,Perkin Trans.

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