Chemical Engineering in Medicine by Gould R.F. (ed.)

By Gould R.F. (ed.)

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E. assembled together in a different order) for the next day’s print run. Thus, when considering verbal communication Butler wrote [23]: The spoken symbol … perishes instantly without material trace, and if it lives at all does so only in the minds of those who heard it. The range of its action is no wider than that within which a voice can be heard; and every time a fresh impression is wanted the type must be set up anew. 14 Chapter 1 Informational Macromolecules In 1764 Koëlreuter in Germany deduced from plant breeding studies that maternal and paternal contributions to offspring were equal.

Fig. 2-1. Double helix model for DNA. ’ Bases are arranged internally so that an A on one strand pairs with a T on the other strand (and vice versa), and a G on one strand pairs with a C on the other strand (and vice versa). The bases are attached to the strands by strong bonds, whereas the base-pairing interactions involve weak bonds (shown as dashed lines). Chemically, the bases are like flat discs that ‘stack’ on top of each other within the helical strands, like a pile of coins (rouleau). These stacking interactions stabilize the double-helical structure and, being largely entropy-driven (see Chapter 15), become greater as temperature increases.

In 1952 Canadian biochemist Gerard Wyatt went further, suggesting a spiral structure [4]: If you have a spiral structure … [it is quite possible to have the bases] sticking out free so that they don’t interfere with each other. Then you could have a regular spacing down the backbone of the chain, in spite of the differences in sequence. Later he added [5]: One is tempted to speculate that regular structural association of nucleotides of adenine with those of thymine and those of guanine with those of cytosine ...

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